Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl

Materials Physics and Chemistry

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Title Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl
 
Creator Usubaliyev, B. T.
Taghiyev, D. B.
Munshiyeva, M. K.
Aliyeva, G. M.
Aliyeva, F. B.
Rzayeva, A. K.
Hasanova, M. M.
Safarova, P. S.
Mammadova, G. Z.
 
Subject Compound; Adduct; Thermal Destruction; Chemical Formula; Crystal Structure
 
Description An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acid-ic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2 (dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.
 
Publisher PiscoMed Publishing Pte Ltd
 
Contributor
 
Date 2019-05-22
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion

 
Format application/pdf
 
Identifier http://ojs.piscomed.com/index.php/MPC/article/view/583
10.18282/mpc.v1i3.583
 
Source Materials Physics and Chemistry; Vol 1 , No 3 (Published); 23-28
2661-412X
 
Language eng
 
Relation http://ojs.piscomed.com/index.php/MPC/article/view/583/537
 
Rights Copyright (c) 2019 B. T. Usubaliyev et al.
http://creativecommons.org/licenses/by-nc/4.0
 

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