Oxidative Study of Benzaldehyde by Isoqauinolinium Bromo Chromate

JOURNAL OF ADVANCES IN CHEMISTRY

View Publication Info
 
 
Field Value
 
Title Oxidative Study of Benzaldehyde by Isoqauinolinium Bromo Chromate
 
Creator Dwivedi, Arun Kumar
Sharma, K. N.
Dwivedi, Arvind Prasad
 
Subject kinetics
Stoichiometry
Excellent
Photosensitivity
Errror
 
Description The kinetics analysis of the oxidative reaction between benzaldehyde and oxidant is quinolinium Bromo chromate was reported in aqueous 40% acetic acid medium at 313 K. The rate of reaction varies first-power of [IQBC] and [H2SO4], whereas fractional-order kinetics was observed for benzaldehyde. The rate constant gradually increases with decrease in dielectric constant of the medium. The neutral salt does not alter the rate. The metal cations (Cu++) slightly accelerate the rate of oxidation when added to reaction mixture. The study rules out the participation of keto form of substrate in complex formation. Benzoic acid was identified as the end-product in stoichiometrically 1:1 based mechanism. The rate law was derived in accordance with the kinetic results.
 
Publisher KHALSA PUBLICATIONS
 
Date 2019-04-30
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Peer-reviewed Article
 
Format application/pdf
 
Identifier http://rajpub.com/index.php/jac/article/view/8248
10.24297/jac.v16i0.8248
 
Source JOURNAL OF ADVANCES IN CHEMISTRY; Vol. 16 (2019); 5354-5359
2321-807X
 
Language eng
 
Relation http://rajpub.com/index.php/jac/article/view/8248/7740
 
Rights Copyright (c) 2019 Arun Kumar Dwivedi, K. N. Sharma, Arvind Prasad Dwivedi
https://creativecommons.org/licenses/by/4.0
 

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