ENTHALPIES OF FORMATION OF FREE RADICALS – REACTION INTERMEDIATES IN LIGNIN PYROLYSIS

Journal of Applied Chemical Science International

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Field Value
 
Title ENTHALPIES OF FORMATION OF FREE RADICALS – REACTION INTERMEDIATES IN LIGNIN PYROLYSIS
 
Creator PONOMAREV, D. A.
METTEE, H. D.
 
Description It is demonstrated that enthalpies of formation for a number of carbon and oxygen centered aromatic free radicals related to lignin can be easily calculated arithmetically. The calculations are based on the assumption that enthalpy of formation for a given radical can be calculated from the experimental value for appropriate unsubstituted free radical taking into account i) the contribution in enthalpy of formation caused by substituent and ii) the correction term which reflects an electronic effect of substituent. The latter can be calculated from the data on relative free radical stability.
 
Publisher International Knowledge Press
 
Date 2015-07-13
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
 
Format application/pdf
 
Identifier http://www.ikprress.org/index.php/JACSI/article/view/3276
 
Source Journal of Applied Chemical Science International; 2015 - Volume 3 [Issue 4]; 158-168
2395-3713
 
Language eng
 
Relation http://www.ikprress.org/index.php/JACSI/article/view/3276/3059
 
Rights Copyright (c) 2015 © Copyright International Knowledge Press. All rights reserved.
 

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